An investigation of organotin compound contamination in three harbors along southeast coast of China

HUANG Chang-jiang; DONG Qiao-xiang; LEI Zan; WANG Zhuang-xiong; ZHOU Kai

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Article Navigation > Haiyang Xuebao > 2005 > 27(1): 57-63

HUANG Chang-jiang, DONG Qiao-xiang, LEI Zan, WANG Zhuang-xiong, ZHOU Kai. An investigation of organotin compound contamination in three harbors along southeast coast of China[J]. Haiyang Xuebao, 2005, 27(1): 57-63.

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An investigation of organotin compound contamination in three harbors along southeast coast of China

1.
Institute of Aquatic Techneque and Environmental Resources Protection, Shantou University, Shantou 515063, China
2.
Institute of Aquatic Techneque and Environmental Resources Protection, Shantou University, Shantou 515063, China;Aquaculture Research Station of Louisiana State University, Baton Rouge, LA 70820, USA
3.
Oceanic and Fishering Environment Monitoring Station of Shenzhen, Shenzhen 518067, China

Received Date: 2003-08-24
Rev Recd Date: 2003-11-25

Abstract

Abstract

Using headspace solid phase microextraction combined with gas chromatography and flame photom etric detector,organotin compounds in water,bottom soil and marine gastropod (Thais clavigera) are invest igated at 21 sampling stations in three hobors (Xiamen,Shantou,and Huiyang) along southeast coast of China from November 2001 to August 2002.The results show that the concentrations of monobutyltin (MBT) in most of samples are the highest,followed by tributyltin (TBT),but dibutyltin is a mlost under detect limit.The concentrations of TBT varied from below detect lmiit to 9.8 ng /dm³ in water samples,0.3~174.7 ng/g(dw) in bottom soil,and 2.1~23.0 ng/g(ww) in marine gastropods.TBT is highest in the water samples from Huiyang Hobor,but in bottom soils and marine gastropods the highests are all found in the samples from Xiamen Harbor.The factors to a ffect concentration of organotins and its special distribution are ship throughput and hydrological condition in each harbor,investigated season,and distance from sampling station to large-scale dock.Based on the data in the present and correlative studies,organotin contamination along Chinese Coast would be universal and serious,and have showed adverse effect on ecosystem,especial to marince gastropods.
- organotin,
- headspace solid phace microex traction,
- southeast coast of China,
- miposex,
- Xiamen Harbor,
- Shantou Harbor

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References

周名江,李正炎,颜天,等.海洋环境中的有机锡及其对海洋生物的影响[J].环境污染治理技术与设备,1994,2(4):67-76.

江桂斌,徐福正,何滨,等.有机锡化合物测定方法研究进展[J].海洋环境科学,1999,18(3):61-66.

周群芳,江桂斌.山东烟台海水样品中有机锡化合物的气相色谱-表面发射火焰光度法测定[J].海洋学报,2000,22(8):391-396.

袁东星,钟树明,杨东宁.厦门西港和闽江口表层沉积物中有机锡含量分布[J].台湾海峡,2001,20(1):91-95.

黄业茹,施钧慧,任剑璋,等.海水及鲈鱼中有机锡的GC-MS分析[J].分析测试技术与仪器,1999,5(2):70-73.

施华宏,黄长江.海产腹足类性畸变现象的形态特征[J].台湾海峡,2001,20(4):552-555.

施华宏,黄长江,谢文勇.用疣荔枝螺性畸变监测海洋有机锡污染的方法初探[J].海洋环境科学,2002,21(4):37-41.

施华宏.中国沿海海产腹足类性畸变及有机锡污染的生物监测[D].广州:暨南大学,2003.1-159.

雷瓒,黄长江,贾丽,等.顶空固相微萃取-气相色谱测定沿海港口表层沉积物中三丁基锡化合物[J].分析测试学报,2003,22(4):28-30.

Idex of/shuiluys/yanhai.中华人民共和国交通部网页(www.moc.gov.cn/shuiluys/yanhai/).

MILLAN E,PAWLISZYN J.Determination of butyltin species in water and sediment by solid-phase microextraction-gas chromatography-flame ionization detection [J].J Chromatography A,2000,873(1):63-71.

PETER F S,ALDIS O V,RICHARD F L.Degradation of tributyltin in San Diego Bay,California,Waters [J].Environ Sci Technol,1986,20(12):1 229-1235.

黄国兰,陈志琼,戴树桂.丁基锡化合物在水体悬浮颗粒物上的吸附行为研究[J].环境科学学报,1998,18(2):137-140

STEWARD C,MORA S J.A review of the degradation of Tributyltin in the marine environment [J].Environ Technol,1990,11:565-570.

SCHNNAAK W,KUCHLER T,KUJAWA M,et al.Organic contaminants in aewage sludge and their ecotoxicological significance in the agricultural utilization of sewage sludge [J].Chemosphere,1997,35(1/2):5-11.

汕头市情.汕头市人民政府办公室网页(http://www.gdst.gov.cn/stsq).

施华宏,黄长江.有机锡污染与海产腹足类性畸变[J].生态学报,2001,21(10):1 711-1 717.

BACCI E,GAGGI C.Organotin compounds in harbor and marina waters from the northern Tyrrhenian Sea [J].Marine Pollution,1989,20(6):290-292.

DIEZ S,ABALOS M,BAYONA J M.Organotin contamination in sediments from the Western Mediter-ranean enclosures following 10 years of TBT regulation [J].Water Res,2002,36:905-918.

MOLLERET M D.Tributyltin in the environment-sources,fate and determination an assessment of present status and research needs [J].Chemosphere,1989,18(9/10):2 015-2 042.

EVANS M,LEKSONA T,MCKINNELL P.Tributyltin pollution:A diminishing problem following legislation limiting the use of TBT-based anti-fouling paints [J].Mar Poll B,1995,30(1),14-21.

SAINT-LOUIS R,GOBERL C,PELLE RTIER E.Tributyltin and its degradation products in the St Lawrence estuary (Canada) [J].Environ Technol,1997,18(12):1 209-1 218.

CEULEMANS M,SLAETS S,ADAMS F.Speciation of organotin in environmental sediment samples [J].Talanta,1998,46:395-405.

SHAWKY S,EMONS H.Distributions pattern of organotin compounds at different trophiclevers of aquatic ecosystems [J].Chemosphere,1998,36 (3):523-535.

FOLSVIK N,BERGE J A,BREVIK E M,et al.Quantification of organo-tin compounds and determination of imposex in populations of dogwhelks(Nucella Lapillus) from Norway [J].Chemosphere,1999,38(3):681-691

HWANGA H M,OH J R,KAHANG S,et al.Tributyltin compounds in mussels,oysters and sediments of Chinhae Bay,Korea[J].MarEnviron Res,1999,47(1):61-70.

TANABE S.Butyltin contamination in marine mammals-a review[J].Mar Poll B,1999,39(1):62-72.

VELL A J,MONTOFF B,AXIAK V.Analytical aspects of the gas chromato-graphic determination of tributyltin and metabolites in environmental samples [J].Sci Total Environ,2000,258:81-88.

ELGETHUN K,NEWMANN C,BLAKE P.Butyltins in shellfish,finfish,water and sediment from the Coos Bay estuary (Oregon,USA) [J].Chemosphere,2000,41:953-964.

刘稷燕,江桂斌,徐明德.南极长城湾附近和台湾以南部分海域水样中丁基锡化合物分析[J].环境科学学报,2002,22(2):267-269.

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