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Zhou Peiyu, Chen Changshu, Hu Ping, Ye Jianjun, Shangguan Maosen, Liu Jingqin, Wu Lingling, Fang Hongda, Huang Chuguang. Oil fingerprinting of polyaromatic hydrocarbons applied to the identification study of oil spill from ship[J]. Haiyang Xuebao, 2014, 36(12): 91-102. doi: 10.3969/j.issn.0253-4193.2014.12.009
Citation: Zhou Peiyu, Chen Changshu, Hu Ping, Ye Jianjun, Shangguan Maosen, Liu Jingqin, Wu Lingling, Fang Hongda, Huang Chuguang. Oil fingerprinting of polyaromatic hydrocarbons applied to the identification study of oil spill from ship[J]. Haiyang Xuebao, 2014, 36(12): 91-102. doi: 10.3969/j.issn.0253-4193.2014.12.009

Oil fingerprinting of polyaromatic hydrocarbons applied to the identification study of oil spill from ship

doi: 10.3969/j.issn.0253-4193.2014.12.009
  • Received Date: 2014-05-19
  • Rev Recd Date: 2014-06-25
  • Differences in the nature of fuel oil and crude oil which are main oil types in marine oil spill determine the different identification methods,so it is significative to seek a suitable method for oil spill identification from the ship. The comparative oil fingerprinting characteristic analysis of polyaromatic hydrocarbons between the spilled oil samples and the suspected oils from ships had been carried on using gas chromatography/mass spectrometry(GC/MS) as a primary analysis method after the samples were separated by the column chromatography method,and the oil source was traced successfully in the oil spill from the ship took place in Pearl River estuary by inner component triangular diagram and cluster analysis based on aromatic hydrocarbon parameters. The results showed that the aromatic oil fingerprinting of the sample from the fourth ship was the most similar with the spilled oil sample,so the oil spill was caused by the fourth ship. The characteristic of aromatic compounds is the main evidence of these weathered oil spill identification because the aromatics were of higher levels and richer variety than saturated hydrocarbons. The key was that the different behavior performed by the organic molecules in oils after undergoing weathering should be fully considered when using oil fingerprinting parameters for the oil spill identification. So,the oil fingerprinting of polyaromatic hydrocarbons are effective for identification of oil spill from the ship.
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