Occurrence mechanism of redox sensitive elements in columnar sediments in South Central Okinawa Trough and their environmental implications

Xu Xiaoyan; Dou Yanguang; Zhang Yong; Chen Xiaohui; Sun Zhilei; Bai Fenglong; Zhai Bin; Wang Libo; Zou Liang

doi:10.12284/hyxb2022186

Volume 44 Issue 10

Oct. 2022

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Xu Xiaoyan，Dou Yanguang，Zhang Yong, et al. Occurrence mechanism of redox sensitive elements in columnar sediments in South Central Okinawa Trough and their environmental implications[J]. Haiyang Xuebao，2022, 44(10)：63–79 doi: 10.12284/hyxb2022186

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Occurrence mechanism of redox sensitive elements in columnar sediments in South Central Okinawa Trough and their environmental implications

doi: 10.12284/hyxb2022186

Xu Xiaoyan^{1, 2
,},
Dou Yanguang^{2, 3
,
,},
Zhang Yong^{2, 4},
Chen Xiaohui^{2, 4},
Sun Zhilei^{2, 4},
Bai Fenglong^{2, 4},
Zhai Bin^{2, 4},
Wang Libo^{2, 4},
Zou Liang^{2, 4}

1.
College of Marine Science and Technology, China University of Geosciences (Wuhan), Wuhan 430074, China
2.
Qingdao Institute of Marine Geology, China Geological Survey, Qingdao 266237, China
3.
Laboratory for Marine Geology, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China
4.
Laboratory for Marine Mineral Resource, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China

Received Date: 2022-02-09
Rev Recd Date: 2022-06-22

Available Online: 2022-07-12

Publish Date: 2022-10-01

Abstract

Abstract

Changes in the content of redox sensitive elements (RSE) in sediments are good surrogate indicators for the redox environment of the overlying water. The RSE in the columnar sediments under complex environmental backgrounds through the grain size, total organic carbon and total nitrogen and its isotopes contents, and redox sensitive elements contents of the two columnar sediments (30 cm) in South Central Okinawa Trough are explored in this paper. And to explore the occurrence mechanism and environmental indication significance. The study found that in addition to the depletion of Cr in the columnar sediments, other RSEs showed different degrees of enrichment. The “grain size effect” has little effect on the RSE content of columnar sediments in the Okinawa Trough; analysis and judgment show that seawater surface productivity is the main factor affecting the redox environment of sediments, and RSE is achieved through the adsorption or desorption of Mn (hydrogen) oxides enrichment and loss. Indicators such as δCe, V/(V+Ni), Ni/Co and V/Cr indicate that the sediment is in an oxic-dysoxic water environment. The Mn element in the sediment diffuses upward in the form of Mn²⁺ through reduction, and is oxidized and enriched by oxygen-containing interstitial water at 25−30 cm to form a manganese peak. The 0−25 cm columnar sediment is in an oxic water column, and 25−30 cm is in a dysoxic water column.
- environmental implications,
- redox sensitive element,
- Mn (hydrogen) oxide,
- columnar sediments,
- Okinawa Trough

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References(96)

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