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南海珠江口盆地深部烃类微渗漏的分子地球化学揭示

茅晟懿,  朱小畏,  苏明,  管红香,  孙永革,  吴能友

文章导航 > 海洋学报  > 2014 >  36(8): 19-29
茅晟懿, 朱小畏, 苏明, 管红香, 孙永革, 吴能友. 南海珠江口盆地深部烃类微渗漏的分子地球化学揭示[J]. 海洋学报, 2014, 36(8): 19-29. doi: 10.3969/j.issn.0253-4193.2014.08.003
引用本文: 茅晟懿, 朱小畏, 苏明, 管红香, 孙永革, 吴能友. 南海珠江口盆地深部烃类微渗漏的分子地球化学揭示[J]. 海洋学报, 2014, 36(8): 19-29. doi: 10.3969/j.issn.0253-4193.2014.08.003
shu
Mao Shengyi, Zhu Xiaowei, Su Ming, Guan Hongxiang, Sun Yongge, Wu Nengyou. Molecular geochemical identification of hydrocarbon microleakage in the Pearl River Mouth Basin of the South China Sea[J]. Haiyang Xuebao, 2014, 36(8): 19-29. doi: 10.3969/j.issn.0253-4193.2014.08.003
Citation: Mao Shengyi, Zhu Xiaowei, Su Ming, Guan Hongxiang, Sun Yongge, Wu Nengyou. Molecular geochemical identification of hydrocarbon microleakage in the Pearl River Mouth Basin of the South China Sea[J]. Haiyang Xuebao, 2014, 36(8): 19-29. doi: 10.3969/j.issn.0253-4193.2014.08.003
shu

南海珠江口盆地深部烃类微渗漏的分子地球化学揭示

doi: 10.3969/j.issn.0253-4193.2014.08.003
  • 1.

    中国科学院 广州能源研究所, 广东 广州 510640;中国科学院 广州天然气水合物研究中心, 广东 广州 510640

  • 2.

    中国科学院 广州地球化学研究所, 广东 广州 510640;中国科学院 广州天然气水合物研究中心, 广东 广州 510640

  • 3.

    浙江大学 地球科学系, 浙江 杭州 310027

基金项目: 国家重点基础研究计划（2009CB219506）；国家自然科学基金（41103043，41303067）；中国科学院广州能源研究所所长基金（y107r71001）；有机地球化学国家重点实验室开放基金（OGL-201209）。

Molecular geochemical identification of hydrocarbon microleakage in the Pearl River Mouth Basin of the South China Sea

  • 1.

    Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China

  • 2.

    Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China

  • 3.

    Department of Geosciences, Zhejiang University, Hangzhou 310027, China

    摘要
  • 摘要: 对南海珠江口盆地Site4B站位柱状沉积物可溶有机质中正构烷烃进行详细分析，结果显示海底以下65~70 cm、80~85 cm和85~90 cm存在明显的似成熟烃类分布。在气相色谱质谱图上（GC-MS），该处存在明显的UCM分布；在烃类分布上，该处以可溶有机质中高碳数正构烷烃奇偶优势趋于消失为特征，CPI为1.15~1.45。同时，整个剖面其他层段沉积有机质中可溶烃类仍以典型的近/现代沉积有机质输入为标志。结合区域地质背景，以及该区域天然气水合物的勘探发现事实，推断Site4B站位海底以下65~70 cm、80~85 cm和85~90 cm烃类异常可能系深部烃类微渗漏所致。
    Abstract: N-alkane components are studied in Site4B profile sediment from the Pearl River Mouth Basin,northern South China Sea,and the results reveal that "similar mature hydrocarbon" distribution is exhibited from 65 cm to 70 cm,80 to 85 cm and 85 cm to 90 cm below the sea floor. An unresolved complex mixture (UCM) of components dominates the gas chromatography mass spectrum (GC-MS) and high molecular weight n-alkanes trend to show no odd predominace with CPI from 1.15 to 1.45 in these layers. Meanwhile,in other layers,alkanes are characteristic of modern/recent organic matter inputs in the profile. Combined with regional geological background and the exploration of gas hydrate in this area,we may conclude that unusual distribution of alkane from 65 cm to 70 cm,80 to 85 cm and 85 cm to 90 cm below the sea floor is resulted by deep hydrocarbon microleakage.
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    • 参考文献(88)
  • Benedetti M,Gorbi S,Fattorini D,et al. Environmental hazards from natural hydrocarbons seepage: Integrated classification of risk from sediment chemistry,bioavailability and biomarkers responses in sentinel species[J]. Environmental Pollution,2014,185: 116-126.
    Nesbitt E A,Martin R A,Campbell K A. New records of Oligocene diffuse hydrocarbon seeps,northern Cascadia Margin[J]. Palaeogeography,Palaeoclimatology,Palaeoecology,2013,390: 116-129.
    Logan G A,Jones A T,Kennard J M,et al. Australian offshore natural hydrocarbon seepage studies,a review and re-evaluation[J]. Marine and Petroleum Geology,2010,27(1): 26-45.
    Dimitrov L I. Mud volcanoes-the most important pathway for degassing deeply buried sediments[J]. Earth-Science Reviews,2002,59(1/4): 49-76.
    Milkov A V,Sassen R,Apanasovich T V,et al. Global gas flux from mud volcanoes: a significant source of fossil methane in the atmosphere and the ocean[J]. Geophysical Research Letters,2003,30: 1037,doi: 10.1029/2002GL016358.
    Mazurenko L L,Soloviev V A. Worldwide distribution of deep-water fluid venting and potential occurrences of gas hydrate accumulations[J]. Geo-Marine Letters,2003,23(3/4): 162-176.
    胡忠良,肖贤明,黄保家,等. 琼东南盆地崖13-1气田气源区圈定与成藏运聚模式[J].地球化学,2005,34(1): 66-72.
    张功成,米立军,吴时国,等. 深水区-南海北部大陆边缘盆地油气勘探新领域[J]. 石油学报,2007,28(2): 15-21.
    Zhu W L,Huang B J,Mi L J,et al. Geochemistry,origin,and deep-water exploration potential of natural gases in the Pearl River Mouth and Qiongdongnan basins,South China Sea[J]. AAPG Bulletin,2009,93(6): 741-761.
    吴能友,张海啟,杨胜雄,等. 南海神狐海域天然气水合物成藏系统初探[J]. 天然气工业,2007,27(9): 1-6.
    吴能友,杨胜雄,王宏斌,等. 南海北部陆坡神狐海域天然气水合物成藏的流体运移体系[J]. 地球物理学报,2009,52(6): 1641-1650.
    徐华宁,邢涛,王家生,等. 利用多道地震反射数据探测神狐海域渗漏型水合物[J]. 地球科学 (中国地质大学学报),2012,37(S1): 195-202.
    谢蕾,王家生,吴能友,等. 南海北部神狐海域浅表层沉积物中自生黄铁矿及其泥火山指示意义[J]. 中国科学: 地球科学,2013,43(3): 351-359.
    吴时国,龚跃华,米立军,等. 南海北部深水盆地油气渗漏系统及天然气水合物成藏机制研究[J]. 现代地质,2010,24(3): 433-440.
    Macdonald I R,Leifer I,Sassen R,et al. Transfer of hydrocarbons from natural seeps to the water column and atmosphere[J]. Geofluids,2002,2(2): 95-107.
    Booth J S,Rowe M M,Fischer K M. Offshore gas hydrate sample database,U. S[J]. Geological Survey Open-File Report,1996,96: 1-17.
    Sassen R,Sweet S T,Milkov A V,et al. Stability of thermogenic gas hydrate in the Gulf of Mexico: Constraints on models of Climate Change [C]//Paull C K,Dillon W P. Natural gas hydrates: Occurrence,distribution,and detection. Washington DC: American Geophysical Union,2001: 131-143.
    Kornacki A S,Kendrick J W,Berry J L. Impact of oil and gas vents and slicks on petroleum exploration in the deepwater Gulf of Mexico[J]. Geo-Marine Letters,1994,14(2/3): 160-169.
    Bence A E,Kvenvolden K A,Kennicutt M C. Organic geochemistry applied to environmental assessments of Prince William Sound,Alaska,after the Exxon Valdez oil spill-a review[J]. Organic Geochemistry,1996,24(1): 7-42.
    Venkatesan M I,Kaplan I R. Distribution and transport of hydrocarbons in surface sediments of the alaskan outer continental shelf[J]. Geochimica et Cosmochimica Acta,1982,46(11): 2135-2149.
    Kennicutt M C,Brooks J M,Mcdonald T J. Origins of hydrocarbons in Bering Sea sediments-I. Aliphatic hydrocarbons and fluorescence[J]. Organic Geochemistry,1991,17: 75-83.
    Ten Haven H L,De Leeuw J W,Rullktter J,et al. Restricted utility of the pristane/phytane ratio as a palaeoenvironmental indicator？ [J] Nature,1988,330(6149): 641-643.
    陆红锋,陈芳,廖志良,等. 南海东北部HD196A岩心的自生条状黃铁矿[J]. 地质学报,2007,81(4): 519-525.
    孙珍,庞雄,钟志洪,等. 珠江口盆地白云凹陷新生代构造演化动力学[J]. 地学前缘,2005,12(4): 489-498.
    王家豪,庞雄,王存武,等. 珠江口盆地白云凹陷中央底辟带的发现及识别[J]. 地球科学(中国地质大学学报),2006,31(2): 209-213.
    石万忠,宋志峰,王晓龙,等. 珠江口盆地白云凹陷底辟构造类型及其成因[J]. 地球科学(中国地质大学学报),2009,34(5): 778-784.
    高鹏,秦成岗,全志臻,等. 地球物理技术在珠江口盆地番禺低隆起天然气勘探中的应用[J]. 物探化探计算技术,2011,33(4): 386-393.
    袁立忠,汪瑞良,轩义华,等. 陆架坡折带PY气田珠江组泥岩盖层特征及对储层含油气性的影响因素研究[J]. 石油天然气学报(江汉石油学院学报),2011,33(3): 62-66,94.
    何永垚,王英民,许翠霞,等. 珠江口盆地深水区白云凹陷气烟囱特征及成藏模式[J]. 海相油气地质,2012,17(3): 62-66.
    轩义华,袁立忠,汪瑞良,等. 番禺低隆起坡折带储层含气性综合预测技术[J]. 地质勘探,2010,30(8): 17-20.
    Bray E E,Evans E D. Distribution of n-paraffins as a clue to recognition of source beds[J]. Geochimica et Cosmochimica Acta,1961,22(1): 2-15.
    Clark R C,Blumer M. Distribution of n-paraffins in marine organisms and sediment[J]. Limnology and Oceanography,1967,12(1): 79-87.
    Meyers P A. Applications of organic geochemistry to paleolimnological reconstructions: A summary of examples from the Laurentian Great Lakes[J]. Organic Geochemistry,2003,34(2): 261-289.
    Cranwell P A. Chain-length distribution of n-alkanes from lake sediments in relation to post-glacial environmental change[J]. Freshwater Biology,1973,3(3): 259-265.
    Kuhn T K,Krull E S,Bowater A,et al. The occurrence of short chain n-alkanes with an even over odd predominance in higher plants and soils [J]. Organic Geochemistry,2010,41(2): 88-95.
    Han J,Calvin M. Occurrence of C22-C25 isoprenoids in Bell Creek crude oil[J]. Geochimica et Cosmochimica Acta,1969,33(6): 733-742.
    Jones J G,Young B V. Major paraffin constituents of microbial cells with particular references to Chromatium sp.[J]. Archives of Microbiology,1970,70(1): 82-88.
    Han J,Mccarthy E D,Van Hoeven W,et al. Organic geochemical studies:Ⅱ. A preliminary report on the distribution of aliphatic hydrocarbons in algae,in bacteria,and in a recent lake sediment[J]. Proceedings of the National Academy of Science of the United States of America,1980,59(1): 29-33.
    朱小畏,茅晟懿,吴能友,等. 神狐海域Site4B表层沉积物中脂肪酸组成及其碳同位素分布特征[J]. 海洋学报,2013,35(6): 75-85.
    Gough M A,Rowland S J. Characterization of unresolved complex mixtures of hydrocarbons in petroleum[J]. Nature,1990,344(6267): 648-650.
    Sutton P A,Lewis C A,Rowland S J. Isolation of individual hydrocarbons from the unresolved complex hydrocarbon mixture of a biodegraded crude oil using preparative capillary gas chromatography[J]. Organic Geochemistry,2005,36(6): 963-970.
    Colombo J C,Barreda A,Bilos C,et al. Oil spill in the Rio de la Plata estuary,Argentina: Ⅰ. Biogeochemical assessment of waters,sediments,soils and biota[J]. Environmental Pollution,2005,134(2): 277-289.
    Martins L K P,Nascimento I A,Fillmann G,et al. Lysosomal responses as a diagnostic tool for the detection of chronic petroleum pollution at Todos os Santos Bay,Brazil[J]. Environmental Research,2005,99(3): 387-396.
    Hu L M,Guo Z G,Feng J L,et al. Distributions and sources of bulk organic matter and aliphatic hydrocarbons in surface sediments of the Bohai Sea,China[J]. Marine Chemistry,2009,113(3/4): 197-211.
    Scarlett A,Galloway T S,Rowland S J. Chronic toxicity of unresolved complex mixtures (UCM) of hydrocarbons in marine sediments[J]. Journal of Soils and Sediments,2007,7(4): 200-206.
    Doskey P V. Spatial variations and chronologies of aliphatic hydrocarbons in Lake Michigan sediments[J]. Environmental Science and Technology,2001,35(2): 247-254.
    Reddy C M,Eglinton T I,Hounshell A,et al. The west Falmouth oil spill after thirty years: the persistence of petroleum hydrocarbons in March sediments[J]. Environmental Science and Technology,2002,36(22): 4754-4760.
    Wakeham S G,Forrest J,Masiello C A,et al. Hydrocarbons in Lake Washington sediments: a 25-year retrospective in an urban lake[J]. Environmental Science and Technology,2004,38(2): 431-439.
    Donkin P,Smith E L,Rowland S J. Toxic effects of unresolved complex mixtures of aromatic hydrocarbons accumulated by mussels,Mytilus edulis,from contaminated field sites[J]. Environmental Science and Technology,2003,37(21): 4825-4830.
    Booth A M,Sutton P A,Lewis C A,et al. Unresolved complex mixtures of aromatic hydrocarbons: Thousands of overlooked persistent,bioaccumulative,and toxic contaminants in mussels[J]. Environmental Science and Technology,2007,41(2): 457-464.
    Crowe T P,Smith E L,Donkin P,et al. Measurements of sublethal effects on individual organisms indicate community-level impacts of pollution[J]. Journal of Applied Ecology,2004,41(1): 114-123.
    Pereira W E,Hostettler F D,Luoma S N,et al. Sedimentary record of anthropogenic and biogenic polycyclic aromatic hydrocarbons in San Francisco Bay,California[J]. Marine Chemistry,1999,64(1/2): 99-113.
    Fernández P,Vilanova R M,Martínez C,et al. The historical record of atmospheric pyrolytic pollution over Europe registered in the sedimentary PAH from remote mountain lakes[J]. Environmental Science and Technology,2000,34(10): 1906-1913.
    Fabiańska M,Miotliński K,Kowalczyk A. Geochemical features of re-deposited organic matter occurring in fluvioglacial sediments in the Racibórz region (Poland): a case study[J]. Chemical Geology,2008,253(3/4): 151-161.
    Olivella M A,Gorchs R,De Las Heras F X C. Origin and distribution of biomarkers in the sulphur rich Utrillas coal basin-Teruel mining district–Spain[J]. Organic Geochemistry,2006,37(12): 1727-1735.
    Wenger L M,Isaksen G H. Control of hydrocarbon seepage intensity on level of biodegradation in sea bottom sediments[J]. Organic Geochemistry,2002,33(12): 1277-1292.
    Abrams M A. Significance of hydrocarbon seepage relative to petroleum generation and entrapment[J]. Marine and Petroleum Geology,2005,22(4): 457-477.
    吴庆余,殷实,盛国英,等. 发现于浮游硅藻中的长链正烷烃[J]. 科学通报,1992,37(24): 2266-2269.
    Volkman J K,Eglinton G,Comer E D S,et al. Long-chain alkenes and alkenones in the marine coccolithophorid Emiliania huxleyi[J]. Phytochemistry,1980,19(12): 2619-2622.
    Venkatesan M I,Kaplan I R. The lipid geochemistry of Antarctic marine sediments: Bransfield strait[J]. Marine Chemistry,1987,21(4): 347-375.
    Wehner H,Teschner M,Bosecker K. Chemical reactions and stability of biomarkers and stable isotope ratios during in vitro biodegradation of petroleum[J]. Organic Geochemistry,1986,10(1/3): 463-471.
    成玉,盛国英,闵育顺,等. 珠江三角洲气溶胶中正构烷烃分布规律、来源及其时空变化[J]. 环境科学学报,1999,19(1): 96-100.
    牛红云,赵欣,戴朝霞,等. 南京市大气气溶胶中颗粒物和正构烷烃特征及来源分析[J]. 环境污染与防治,2005,27(5): 363-366.
    唐小玲,毕新慧,陈颖军,等. 广州市空气颗粒物中烃类物质的粒径分布[J]. 地球化学,2005,34(5): 508-514.
    黄云碧. 气相色谱法测定气溶胶中的烃类有机物[J]. 西南科技大学学报,2006,21(2): 75-78.
    胡建芳,彭平安,贾国东,等. 三万年来南沙海区古环境重建: 生物标志物定量与单体碳同位素研究[J]. 沉积学报,2003,21(2): 211-218.
    Johnson R W,Calder J A. Early diagenesis of fatty acids and hydrocarbons in a salt marsh environment[J]. Geochimica et Cosmochimica Acta,1973,37(8): 1943-1955.
    Prince R C,Mcfarlin K M,Butler J D,et al. The primary biodegradation of dispersed crude oil in the sea[J]. Chemosphere,2013,90(2): 521-526.
    Dembicki H Jr. Recognizing and compensating for interference from the sediments background organic matter and biodegradation during interpretation of biomarker data from seafloor hydrocarbon seeps: An example from the Marco Polo area seeps,Gulf of Mexico,USA[J]. Marine and Petroleum Geology,2010,27(9): 1936-1951.
    Ten Haven H L,De Leebw J W,Sinninghe Damste J S,et al. Application of biological markers in the recognition of palaeohypersaline environments [C]//Kelts K,Fleet A J,Talbot M. Lacustrine Petroleum Source Rocks. Oxford: Blackwell Press,1988: 123-130.
    Fang J,Hasiotis S T,Gupta S D,et al. Microbial biomass and community structure of a stromatolite from an acid mine drainage system as determined by lipid analysis[J]. Chemical Geology,2007,243(1/2): 191-204.
    Cowei B R,Slater G F,Bernier L,et al. Carbon isotope fractionation in phospholipid fatty acid biomarkers of bacteria and fungi native to an acid mine drainage lake[J]. Organic Geochemistry,2009,40(9): 956-962.
    Jones J G. Studies on lipids of soil micro-organisms with particular reference to hydrocarbons[J]. Journal of General Microbiology,1969,59(2): 145-152.
    Atlas R M. Microbial degradation of petroleum hydrocarbons: an environmental perspective[J]. Microbiological Reviews,1981,45(1): 180-209.
    Callaghan A V,Tierney M,Phelps C D,et al. Anaerobic biodegradation of n-hexadecane by a nitrate-reducing consortium[J]. Applied and Environmental Microbiology,2009,75(5): 1339-1344.
    Jones D M,Head I M,Gray N D,et al. Crude-oil biodegradation via methanogenesis in subsurface petroleum reservoirs[J]. Nature,2008,451(7175): 176-180.
    Connan J. Biodegradation of crude oils in reservoirs [C]//Brooks J,Welte D H. Advances in Petroleum Geochemistry. London: Academic Press,1984: 299-335.
    Gürgey K. Correlation,alteration,and origin of hydrocarbons in the GCA,Bahar,and Gum Adasi fields,western South Caspian Basin: geochemical and multivariate statistical assessments[J]. Marine and Petroleum Geology,2003,20(10): 1119-1139.
    Leahy J G,Colwell R R. Microbial degradation of hydrocarbons in the environment[J]. Microbiological Reviews,1990,54(3): 305-315.
    Wang Z D,Fingas M F. Development of oil hydrocarbon fingerprinting and identification techniques. Marine Pollution Bulletin,2003,47(9/12): 423-452.
    Hasinger M,Scherr K E,Lundaa T,et al. Changes in iso-and n-alkane distribution during biodegradation of crude oil under nitrate and sulphate reducing conditions[J]. Journal of Biotechnology,2012,157(4): 490-498.
    Abrams M A,Narimanov A A. Geochemical evaluation of hydrocarbons and their potential sources in the western South Caspian depression,Republic of Azerbaijan[J]. Marine and Petroleum Geology,1997,14(4): 451-468.
    Holba A G,Dzou L I P,Hickey J J,et al. Reservoir geochemistry of South Pass 61 Field,Gulf of Mexico: compositional heterogeneities reflecting filling history and biodegradation[J]. Organic Geochemistry,1996,24(12): 1179-1198.
    Masterson W D,Dzou L I P,Holba A G,et al. Evidence for biodegradation and evaporative fractionation in West Sak,Kuparuk and Prudhoe Bay field areas,North slope,Alaska[J]. Organic Geochemistry,2001,32(3): 411-441.
    Matyasik I,Steczko A,Philp R P. Biodegradation and migrational fractionation of oils from the Eastern Carpathians,Poland[J]. Organic Geochemistry,2000,31(12): 1509-1523.
    何云龙,解习农,李俊良,等. 琼东南盆地陆坡体系发育特征及其控制因素[J]. 地质科技情报,2010,29(2): 118-122.
    苏明,解习农,姜涛,等. 琼东南盆地裂后期S40界面特征及其地质意义[J]. 地球科学(中国地质大学学报),2011,36(5): 886-894.
    何云龙,解习农,陆永潮,等. 琼东南盆地深水块体流构成及其沉积特征[J]. 地球科学(中国地质大学学报),2011,36(5): 905-913.
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