48 ka以来日本海古生产力和古氧化还原环境变化的 地球化学记录
The geochemical records of paleoproductivity and paleoredox in the Sea of Japan since 48 ka
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摘要: 通过对日本海Ulleung盆地KCES-1孔元素地球化学分析,探讨了过去48 ka以来日本海古生产力和古氧化还原环境的变化规律和影响因素。多种替代指标质量累积速率(总有机碳、CaCO3,磷、过剩钡、镉含量)显示日本海古生产力自48 ka以来发生了显著的变化。在48~18 ka低海平面和有限的水体交换导致表层水古生产力相对较低。在18~11 ka随着海平面的上升,富营养盐水团(亲潮和东海沿岸流水团)的流入导致古生产力逐渐增大,在12.6~11.5 ka古生产力达到最大值。在全新世对马暖流成为影响古生产力变化的重要因素,并且自5 ka以来古生产力保持相对稳定。古氧化还原替代指标(总有机碳、钼、铀、锰、碳与硫含量之比、自生铀、自生钼含量)显示在12~9 ka日本海底层水可能为无氧环境。古生产力高和底层水体有限的交换是诱发底层水缺氧的主要因素,而这又与全球气候变化和海平面变化有关。Abstract: The paleoproductivity and paleoredox history in the Sea of Japan since 48 ka have been reconstructed using element geochemical data, and factors controlling the change are determined. The mass accumulations of multiproxies show that the paleoprodutivity has varied greatly since 48 ka. At 48~18 ka, a relative lower sea-level and a limited water mass exchange resulted in the lower paleoproductivity. At 18~11 ka, the higher paleoproductivity was resulted from the rich-nutrients water mass (the Oyasio and the East China Sea coastal water) inflowing into the Sea of Japan with relative sea-level rise, and the maximum value was observed at 12.6~11.5 ka. In the Holocene, the Tsushima Warm Current was a main factor that controlled the distribution of paleoproductivity, and since 5 ka the paleoproductivity had remained relative stability.the proxies about the paleoredox (TOC, molybdenum, uranium and manganese , the ratio of carbon to sulfur content, authigenic uranium and molybdenum contents) indicate that at 12~9 ka, the bottom water is anoxic. Both enhanced paleoproductivity and restricted bottom-water advection triggered the bottom water anoxic and it was also related to the global climate change and the sea-level change.
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Key words:
- redox sensitive elements /
- paleoproductivity /
- paleoredox /
- Sea of Japan
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